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S6N5O4, A Compound with Separately Stacked Cyclic Radical Cations S3N and Cyclic Anions S3N3O

✍ Scribed by Prof. Dr. Herbert W. Roesky; Dr. Michael Witt; Jürgen Schimkowiak; Martin Schmidt; Dr. Mathias Noltemeyer; Prof. Dr. George M. Sheldrick

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
204 KB
Volume
21
Category
Article
ISSN
0044-8249

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Capability of [Re III (tu-S) 6 ]Cl 3 , where tu = thiourea, as a precursor to other Re III complexes by ligand substitution in aqueous medium is studied. For the decomposition of [Re(tu-S) 6 ]Cl 3 , experiments suggest pseudo first order kinetics and observed rate constants vary from 1.3 ´10 ±2 to 9