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(S) -TroloxTM methyl ether, a powerful derivatizing reagent for the determination of the enantiomeric purity of chiral alcohols by GC and SFC with achiral columns

✍ Scribed by Wiley Walther; Walter Vetter; Thomas Netscher


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
308 KB
Volume
4
Category
Article
ISSN
1040-7685

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✦ Synopsis


Abstract

The enantiomers of aliphatic alcohols are transformed by a new chiral reagent (S)‐Trolox methyl ether to their diastereomeric esters which are separated by capillary GC or SFC on achiral columns. The applicability of this reagent and its superiority to the hitherto known reagents are demonstrated by selected examples.