(S)-Methyl 4-methyl-2-(1H-pyrrole-2-carboxamido)pentanoate
✍ Scribed by Zeng, Xiang-Chao ;Liu, Po-Run
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 215 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 183 K Mean '(C±C) = 0.005 A Ê R factor = 0.068 wR factor = 0.097 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 9 H 11 BrN 2 O 3 , was synthesized by condensation of glycine ethyl ester with 4-bromo-2-(trichloroacetyl)pyrrole at room temperature in 78.4% yield. In the crystal structure, intermolecular N-HÁ Á ÁO hydrogen-bond interactions link the molecules into two-dimensional sheets.
The molecules of the title compound, C 13 H 13 NO 2 , are close to planar [maximum deviation of 0.0753 (15) A ˚from the leastsquares plane defined by all non-H atoms in the molecule]. Molecules form centrosymmetric dimers through N-HÁ Á ÁO hydrogen bonding. Molecules further associate through edgeto
The title compound, C 8 H 9 BrN 2 O 3 , was synthesized by condensation of -alanine methyl ester with 4-bromo-2-(trichloroacetyl)pyrrole, followed by saponification and acidification. In the molecule, all bond lengths and angles are normal. The crystal packing is stabilized by intermolecular N-HÁ Á