✦ LIBER ✦

Réactions de germylènes avec divers oxirannes et le thiiranne. Mise en évidence de germanones et germathiones intermédiaires. Communication préliminaire

✍ Scribed by Jacques Barrau; Marsan Bouchaut; Hélène Lavayssiere; Gabriel Dousse; Jacques Satgé

Publisher: John Wiley and Sons
Year: 1979
Tongue: German
Weight: 146 KB
Volume: 62
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19790620122

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✦ Synopsis

Abstract

Complexed dialkylgermylenes R~2~GeNR~3~ or R~2~GePy react with oxiranes or thiirane and lead to dialkylgermanone and germathione via germaoxetanes or germathiacyclobutane. The formation of germadioxolanes or germadithiolane finally observed arises from condensation of dialkylgermanone (or germathione) on oxiranes (or thiirane).

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