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Réactions chimiques oscillantes III. Effets de la température et de la composition chimique sur la «période d'induction» des systèmes BrO/Ce4+/Cyclohexanone et BrO/Ce4+/Cyclopentanone

✍ Scribed by par Vincent J. Farage; Désimir Janjic

Publisher
John Wiley and Sons
Year
1980
Tongue
German
Weight
217 KB
Volume
63
Category
Article
ISSN
0018-019X

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✦ Synopsis

Oscillating Chemical Reactions. III. Effects of the Temperature and Chemical Composition on the ‘Induction Period’ of the BrO**/Ce^4+^/Cyclohexanon and BrO****/Ce^4+^/Cyclopentanon Systems**

A study of the influence of the temperature and composition of the BrO/Ce^4+^/cyclohexanon (S1) and BrO/Ce^4+^/cyclopentanon (S2) systems has shown a very particular behaviour for τ~ind.~ for a given ratio α of concentrations:
Moreover, for 0.27 ⩽ α ⩽ 0.32, log^1^/τ~ind.~ is no longer a linear function of the inverse of the temperature: a break in the line log^1^/τ~ind.~ = f(1/T) occurs.

📜 SIMILAR VOLUMES

Réactions chimiques oscillantes. II. Com
Réactions chimiques oscillantes. II. Comportement de la «période d'induction» dans les systémes BrO/Ce4+/Cyclohexanone et BrO/Ce4+/Cyclopentanone
✍ Vincent J. Farage; DéSimir Janjic 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 285 KB

Suisse) (13.XII. 77) Oscillating Chemical Reactions. 11. Behaviour of the "induction period" in the BrO~/Ce4+/Cyclohexanon and Br0~/Ce4+/Cyclopentanon systems ## Summary 1) The addition of a-monobromoketone, one of the products of reaction of the BrO~/Ce4+/Cyclohexanon (Sl) and BrO:/Ce4+/Cyclopen