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Rydberg states of acetylene clusters (C2H2)2 and (C2H2)3 resolved by two-photon resonant ionization spectroscopy

✍ Scribed by Y.F. Zhu; S.L. Allman; R.C. Phillips; W.R. Garrett; C.H. Chen

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 812 KB
Volume: 224
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00529-x

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✦ Synopsis

The Rydberg states of the acetylene clusters ( C2H2)a and (C,H,), have been resolved by the technique of twophoton resonant ionization spectroscopy in the energy region of the monomer gerade Rydberg states. The stability of these cluster Rydberg states has been found to be vibrational mode dependent. The geometry of the clusters, and the mechanism of the dissociative ionization have been discussed.

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