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Rydberg series of atomic He by opto-galvanic spectroscopy

✍ Scribed by D.H. Katayama; J.M. Cook; V.E. Bondybey; Terry A. Miller


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
511 KB
Volume
62
Category
Article
ISSN
0009-2614

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✦ Synopsis


Atomic helmm trzmsitioas from its met.xstzkble 3s 'S stctte to hi$ IIP 'P 01 = 14 to 36) Rldberg states ha\c been obsened \ia opto&vanic speclroxop_r for the fi:sr ttme. The observed transition frequenciesagree ~~11 \ith predictions of quantum defecr theory indrL;lrins the states are not strongly perturbed mternalI_v or by their cnrironment. The It\els are slightly broadened by He coliisions xtd stay electric fields.


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Orbital relaxation in the Rydberg series
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The orbital behavior of both the singlet and triplet Rydberg series for lsns configurations of the He atom has been investigated using one-and two-configuration Hartree-Fock wave functions. The core orbital within the triplet series changes negligibly; however, a contract trend is noticeable as the