The orbital behavior of both the singlet and triplet Rydberg series for lsns configurations of the He atom has been investigated using one-and two-configuration Hartree-Fock wave functions. The core orbital within the triplet series changes negligibly; however, a contract trend is noticeable as the
β¦ LIBER β¦
Rydberg series of atomic He by opto-galvanic spectroscopy
β Scribed by D.H. Katayama; J.M. Cook; V.E. Bondybey; Terry A. Miller
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 511 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Atomic helmm trzmsitioas from its met.xstzkble 3s 'S stctte to hi$ IIP 'P 01 = 14 to 36) Rldberg states ha\c been obsened \ia opto&vanic speclroxop_r for the fi:sr ttme. The observed transition frequenciesagree ~~11 \ith predictions of quantum defecr theory indrL;lrins the states are not strongly perturbed mternalI_v or by their cnrironment. The It\els are slightly broadened by He coliisions xtd stay electric fields.
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