The laser-induced fluorescence and resonantly enhanced two-photon ionization spectra for the 1 'E: -X 'Z: vibronic transitions of jet-cooled Cl, are observed by using a tunable vacuum ultraviolet laser. A rotational analysis of the (u', u" ) = (39, 0) transitions for '%I2 and 35C137C1 reveals that t
✦ LIBER ✦
Rydberg and ion-pair state mixing in the 1 1Σ+u and 2 3Πu vibronic states of Cl2 as studied by vacuum ultraviolet laser spectroscopy
✍ Scribed by Tsuchizawa, Tai; Yamanouchi, Kaoru; Tsuchiya, Soji
- Book ID
- 121254985
- Publisher
- American Institute of Physics
- Year
- 1990
- Tongue
- English
- Weight
- 990 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.459610
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The optical-optical double-resonance spectroscopy is applied to study the ion-pair states of \(\mathrm{Cl}_{2}\) correlating to \(\mathrm{Cl}^{-}\left({ }^{1} S\right)+\mathrm{Cl}^{+}\left({ }^{3} P_{2}\right)\). In the \((1+2)\) photoexcitation sequence, we gain access to the \(0_{u}^{+}\left({ }^{