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Ruthenium–Indenylidene Olefin Metathesis Catalyst with Enhanced Thermal Stability

✍ Scribed by Dr. Anzhelika Kabro; Dr. Thierry Roisnel; Dr. Cédric Fischmeister; Dr. Christian Bruneau


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
365 KB
Volume
16
Category
Article
ISSN
0947-6539

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## Abstract The four‐coordinate ruthenium phosphonium alkylidenes **1‐Cy** and **1‐__i__Pr**, differing in the substituent on the phosphorus center, were observed to decompose thermally in the presence of 1,1‐dichloroethylene to produce [H~3~CPR~3~][Cl]. The major ruthenium‐containing product was a