The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะC. In the presence of the catalyst, the experimental rate law
Ruthenium(III)- and osmium(VIII)-catalyzed oxidation of 2-thiouracil by bromamine-B in acid and alkaline media: a kinetic and mechanistic study
โ Scribed by Putta Swamy; Nirmala Vaz
- Book ID
- 110438381
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 229 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0340-4285
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๐ SIMILAR VOLUMES
The kinetics of oxidation of aliphatic amines viz., ethylamine, n-butylamine, isopropylamine (primary amines), diethylamine (secondary amine), and triethylamine (tertiary amine) by chloramine-T have been studied in NaOH medium catalyzed by osmium(W1) and in perchloric acid medium with ruthenium(II1)
The kinetics of oxidation of the aliphatic primary amines, n-propylarnine, n-butylarnine, and isoarnylarnine, by sodium N-brornobenzenesulfonarnide or bromamine-B (BAB) in sodium hydroxide medium has been studied at 35" C The reaction rate shows a First-order dependence each on [ BABl and [amine]. a