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Ruthenium(II)-Catalyzed Oppenauer-Type Oxidation of Secondary Alcohols

✍ Scribed by Dr. Maria L. S. Almeida; Dr. Marion Beller; Dr. Guo-Z. Wang; Prof. Jan-E. Bäckvall

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
458 KB
Volume
2
Category
Article
ISSN
0947-6539

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ChemInform Abstract: Ruthenium(II)-Catal
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✍ M. L. S. ALMEIDA; M. BELLER; G.-Z. WANG; J.-E. BAECKVALL 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Ruthenium(II)-Catalyzed Oppenauer-Type Oxidation of Secondary Alcohols. -The title reaction is tested on 11 alcohols and found to be general and compatible with double bonds and oxidation-sensitive aromatics under application of the Ru catalysts depicted. -(ALMEIDA, M. L. S.;

Iron-Catalyzed Oppenauer-Type Oxidation
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## Abstract A (hydroxycyclopentadienyl)iron dicarbonyl hydride catalyzes the Oppenauer‐type oxidation of alcohols with acetone as the hydrogen acceptor. Many functional groups are tolerant to the oxidation conditions. The same complex also catalyzes the dehydrogenation of diols to lactones. A mecha