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Ruthenium(II) Anilido Complex Containing a Bisphosphine Pincer Ligand: Reversible Formation of Amidinate Ligands via Intramolecular C−N Bond Formation

✍ Scribed by Zhang, Jubo; Gunnoe, T. Brent; Boyle, Paul D.

Book ID
126054054
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
87 KB
Volume
23
Category
Article
ISSN
0276-7333

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Sequential C−H and C−Ru Bond Formation a
Sequential C−H and C−Ru Bond Formation and Cleavage during the Thermally Induced Rearrangement of Aryl Ruthenium(II) Complexes with [C 6 H 3 (CH 2 NMe 2 ) 2 -2,6] - as a Bidentate η 2 - C,N Coordinated Ligand. The Crystal Structures of the Isomeric Pairs [RuCl{η 6 -C 10 H 14 }{η 2 - C,N -C 6 H 3 (CH 2 NMe 2 ) 2 -2, n }] ( n = 4 or 6) and [Ru(η 5 -C 5 H 5 ){η 2 - C,N -C 6 H 3 (CH 2 NMe 2 ) 2 -2, n }(PPh 3 )] ( n = 4 or 6)
✍ Steenwinkel, Pablo; James, Stuart L.; Gossage, Robert A.; Grove, David M.; Kooij 📂 Article 📅 1998 🏛 American Chemical Society 🌐 English ⚖ 283 KB