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Ruthenium η 4 -Trimethylenemethane Complexes Containing Tripodal Phosphanomethylamine Ligands

✍ Scribed by Scherl, Peter; Kruckenberg, Achim; Mader, Steffen; Wadepohl, Hubert; Gade, Lutz H.


Book ID
115475148
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
267 KB
Volume
31
Category
Article
ISSN
0276-7333

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The unusual η 2 -coordination of a 1,2,4-triazolato ligand to a transition metal is described. The synthesized compounds 3) and [Cp\*Ti(η 2 -tz) 3 ] (4) (tzH = 3,5-diisopropyl-1,2,4triazole) were characterized by 1 H and 13 C NMR spectroscopy and, in the case of 1 and 2, by X-ray crystallography. Bo