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Ruthenium sulfophthalocyanine catalyst for the oxidation of chlorinated olefins with hydrogen peroxide

✍ Scribed by Mario Bressan; Nicola Celli; Nicola d’Alessandro; Lolita Liberatore; Antonino Morvillo; Lucia Tonucci


Book ID
108356273
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
115 KB
Volume
593-594
Category
Article
ISSN
0022-328X

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📜 SIMILAR VOLUMES


Mntrimethyltriazacyclononane/ascorbic a
✍ Albrecht Berkessel; Christoph A. Sklorz 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 253 KB

The system comprised of manganese(II) acetate or sulfate, 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) and ascorbic acid efficiently catalyzes the epoxidation of olefins and the oxidation of alcohols with hydrogen peroxide. For example, in the presence of as little as 0.03 mol% of Mn 2÷, methyl