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Ruthenium-Mediated Regio- and Stereoselective Alkenylation of Pyridine

✍ Scribed by Murakami, Masahiro; Hori, Seiji


Book ID
126957799
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
61 KB
Volume
125
Category
Article
ISSN
0002-7863

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Regio- and stereoselective copper-induce
✍ JosΓ© Barluenga; Roberto Sanz; Francisco J. FaΓ±anΓ‘s πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 192 KB

N-Allyl-N-(2-1ithioallyl)aniline undergoes intramolecular carbometallation via 5-exo addition on treatment with CuCN. 2-Alkenyl 2-bromophenyl ethers rearrange to 2-(2-alkenyl)pllenols by bromine-lithium exchange and further transmetallation with CuCN.