Ruthenium Hydride Catalyzed Regioselective Addition of Aldehydes to Enones To Give 1,3-Diketones
✍ Scribed by Takahide Fukuyama; Takashi Doi; Satoshi Minamino; Sohei Omura; Ilhyong Ryu
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 112 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract The perchlorate salt of the dicationic bipy–ruthenium complex __cis__‐[Ru(6,6′‐Cl~2~bipy)~2~(H~2~O)~2~]^2+^ effectively catalyzes addition of β‐diketones to secondary alcohols and styrenes to yield the α‐alkylated β‐diketones. In a catalytic addition reaction of acetylacetone to 1‐pheny
## Abstract A modular synthesis of α‐arylated carbonyl compounds has been achieved by the combination of an indium‐catalyzed regioselective addition of β‐keto esters to conjugated diynes and a palladium‐catalyzed benzannulation reaction. Indium tris(bistriflylamide), In(NTf~2~)~3~, was found to be