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Ruthenium Complexes Bearing Bulky Pentasubstituted Cyclopentadienyl Ligands and Evaluation of [Ru(η5-C5Me4R)(MeCN)3][PF6] Precatalysts in Nucleophilic Allylic Substitution Reactions

✍ Scribed by Hui-Jun Zhang; Bernard Demerseman; Zhenfeng Xi; Christian Bruneau


Book ID
102166834
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
161 KB
Volume
2008
Category
Article
ISSN
1434-1948

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✍ Maria Saporita; Giovanni Bottari; Giuseppe Bruno; Dario Drommi; Felice Faraone 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 206 KB

a b s t r a c t [( 5 -C 5 R 5 )Ru(N-N\*)(NCMe)]PF 6 (R = H, N-N\* = (Sa)-1, 5; (Sa)-2, 6; (R,R)-3, 7; (R,R)-4; 8; R = Me, N-N\* = (Sa)-1, 9) complexes containing N-N\* bulky chiral ligands of different rigidity and flexibility were synthesized by reacting the precursor [( 5 -C 5 R 5 )Ru(NCMe) 3 ]PF