✦ LIBER ✦

Ruthenium complexes bearing bidentate Schiff base ligands as efficient catalysts for organic and polymer syntheses

✍ Scribed by Renata Drozdzak; Bart Allaert; Nele Ledoux; Ileana Dragutan; Valerian Dragutan; Francis Verpoort

Book ID: 104010850
Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 847 KB
Volume: 249
Category: Article
ISSN: 0010-8545
DOI: 10.1016/j.ccr.2005.05.003

No coin nor oath required. For personal study only.

✦ Synopsis

A concise overview is given on mononuclear and dinuclear, bidentate Schiff base ruthenium complexes with different additional ligands and on their applications in various chemical transformations such as Kharasch addition, enol-ester synthesis, alkyne dimerization, olefin metathesis and atom transfer radical polymerization. These new ruthenium complexes, conveniently prepared from commonly available ruthenium compounds, are very stable, exhibit a good tolerance towards organic functionalities, air and moisture and display high activity and chemoselectivity in chemical transformations. Relevant features of coordination chemistry connected with the reaction mechanism and chemoselectivity are also fully described. Since the nature of Schiff bases can be changed in a variety of ways, appealing routes for designing and preparing novel ruthenium complexes can be foreseen in the future.

📜 SIMILAR VOLUMES

Ruthenium complexes of Schiff base ligan

Ruthenium complexes of Schiff base ligands as efficient catalysts for catechol–hydrogen peroxide reaction

✍ Pearly Sebastian Chittilappilly; N. Sridevi; K. K. Mohammed Yusuff 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 178 KB

ChemInform Abstract: Ruthenium Complexes

ChemInform Abstract: Ruthenium Complexes Containing Bidentate Schiff Base Ligands as Precursors of Homogeneous and Immobilized Catalysts

✍ Fu Ding; Yaguang Sun; Stijn Monsaert; Renata Drozdzak; Ileana Dragutan; Valerian 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 11 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

A new class of ruthenium complexes conta

A new class of ruthenium complexes containing Schiff base ligands as promising catalysts for atom transfer radical polymerization and ring opening metathesis polymerization

✍ Bob De Clercq; Francis Verpoort 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 128 KB

Polymer-anchored vanadium(IV), molybdenu

Polymer-anchored vanadium(IV), molybdenum(VI) and copper(II) complexes of bidentate ligand as catalyst for the liquid phase oxidation of organic substrates

✍ Mannar R. Maurya; Maneesh Kumar; Umesh Kumar 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 853 KB

New Palladium Complexes with S- or Se-Co

New Palladium Complexes with S- or Se-Containing Schiff-Base Ligands as Efficient Catalysts for the Suzuki—Miyaura Cross-Coupling Reaction of Aryl Bromides with Phenylboronic Acid under Aerobic Conditions.

✍ Ioannis D. Kostas; Barry R. Steele; Aris Terzis; Svetlana V. Amosova; Alexander 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 15 KB 👁 2 views

New Palladium Complexes with S- or Se-Co

New Palladium Complexes with S- or Se-Containing Schiff-Base Ligands as Efficient Catalysts for the Suzuki–Miyaura Cross-Coupling Reaction of Aryl Bromides with Phenylboronic Acid under Aerobic Conditions

✍ Ioannis D. Kostas; Barry R. Steele; Aris Terzis; Svetlana V. Amosova; Alexander 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 1 views

## Abstract Four palladium chelate complexes with S‐ or Se‐containing substituted salicylaldehyde Schiff‐base derivatives have been synthesized. Spectroscopic and crystallographic data indicate that, in the complexes, the deprotonated salicylaldehyde ligand is bound to the metal in an O,N,S (or Se)