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Ruthenium complex catalyzed oxidative conversion of aliphatic amines to carboxylic acids using bromamine-T: Kinetic and mechanistic study

โœ Scribed by C.H. Vinod Kumar; K.N. Shivananda; Rajenahally V Jagadeesh; C. Naga Raju


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
359 KB
Volume
311
Category
Article
ISSN
1381-1169

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The kinetics of oxidation of aliphatic amines viz., ethylamine, n-butylamine, isopropylamine (primary amines), diethylamine (secondary amine), and triethylamine (tertiary amine) by chloramine-T have been studied in NaOH medium catalyzed by osmium(W1) and in perchloric acid medium with ruthenium(II1)