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Ruthenium-Catalyzed Stereoselective Intramolecular Carbenoid C—H Insertion for β- and γ-Lactam Formations by Decomposition of α-Diazoacetamides.

✍ Scribed by Matthew Kwok-Wai Choi; Wing-Yiu Yu; Chi-Ming Che


Publisher
John Wiley and Sons
Year
2005
Weight
39 KB
Volume
36
Category
Article
ISSN
0931-7597

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Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy