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Ruthenium Catalyzed Selective Regio-and-Mono-Allylation of Cyclic 1,3-Diketones Using Allyl Alcohols as Substrates

✍ Scribed by Stefan Gruber; Paul S. Pregosin

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
246 KB
Volume
351
Category
Article
ISSN
1615-4150

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## Abstract Green and fast: Allylation of aromatic and aliphatic thiols, by using allyl alcohols as substrates, requires only minutes at ambient temperature with a Ru catalyst (see scheme). Quantitative conversion is normal and the catalyst possesses high functional‐group tolerance.magnified image