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Ruthenium-catalyzed reductive coupling between ketones and primary alcohols in the presence of ethylenediamine

✍ Scribed by Chan Sik Cho

Book ID: 103834624
Publisher: Elsevier Science
Year: 2007
Tongue: English
Weight: 141 KB
Volume: 267
Category: Article
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2006.11.020

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✦ Synopsis

Ketones are reductively coupled with an array of primary alcohols in dioxane at 80 • C in the presence of a catalytic amount of a ruthenium catalyst along with KOH and ethylenediamine to give the corresponding carbon-carbon coupled secondary alcohols in moderate to good yields.

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