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Ruthenium-Catalyzed Reconstructive Synthesis of Functional Organic Molecules via Cleavage of Carbon—Carbon Bonds

✍ Scribed by Teruyuki Kondo; Take-aki Mitsudo


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✍ Teruhisa Tsuchimoto; Taku Ainoya; Kazuki Aoki; Tatsuya Wagatsuma; Eiji Shirakawa 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 303 KB

## Abstract A pyrrolyl group bound to an sp^3^ carbon atom in __gem__‐dipyrrolylalkanes was found to be successfully replaced by a certain range of carbon nucleophiles in the presence of an indium catalyst. The reaction can also be performed efficiently as a three‐component assembly of alkynes, pyr