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Ruthenium-Catalyzed Oxidation of Allyl Alcohols with Intermolecular Hydrogen Transfer: Synthesis of α,β-Unsaturated Carbonyl Compounds

✍ Scribed by Ren, Kai; Hu, Bei; Zhao, Mengmeng; Tu, Yahui; Xie, Xiaomin; Zhang, Zhaoguo


Book ID
124057957
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
467 KB
Volume
79
Category
Article
ISSN
0022-3263

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Homogeneous catalytic transfer-hydrogena
✍ Yoel Sasson; Jochanan Blum 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 185 KB

Dichlorotris(triphenylphosphine)ruthenium (II), RuC12(PPh3)3, is well known for its ability to catalyze hydrogen transfer in several organic reactions l-10 . We now wish to report the application of this effect to the selective transfer-hydrogenation of a&unsaturated carbonyl compounds. A mixture of