The 1,3-dipolar cycloaddition of trifluoromethylated propargylic alcohols 1 with azides in the presence of catalytic [Cp \* RuCl 2 ] n afforded exclusively 4-trifluoromethyl-1,4,5-trisubstituted-1,2,3-triazoles 2 in high yields.
β¦ LIBER β¦
Ruthenium-Catalyzed Enantioselective [3+3] Cycloaddition of Propargylic Alcohols with 2-Naphthols
β Scribed by Kanao, Keiichiro; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
- Book ID
- 126088019
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 881 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0276-7333
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