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Ruthenium-catalyzed dimerization of acrylonitrile in the presence of carboxylic acids

โœ Scribed by Kohich Kashiwagi; Ryoji Sugise; Toshihiro Shimakawa; Tunao Matuura; Masashi Shirai


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
434 KB
Volume
264
Category
Article
ISSN
1381-1169

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Ruthenium-catalyzed selective anti-Marko
โœ Karen Melis; Pawel Samulkiewicz; Jacek Rynkowski; Francis Verpoort ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 142 KB

Carboxylic acids react with terminal alkynes in the presence of a catalytic amount of RuCl x (p-cymene)(triazol-5-ylidene) to selective generate Z-alk-1-en-1-yl esters. The anti-Markovnikov and trans addition on the terminal alkyne gives access to Z-alkene derivatives of phenylacetylene, t-butylacet