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Ruthenium-Catalyzed Diastereoselective syn-Cyclopropanation of Trisubstituted Alkenes with Diazoacetates

โœ Scribed by Thorsten Werle; Gerhard Maas


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
78 KB
Volume
343
Category
Article
ISSN
1615-4150

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## In the cross-metathesis reaction of tri(methyl, ethoxy)vinylsilanes with propene and/or 1-butene catalyzed by RuCl 2 (PPh 3 ) 3 activated in benzene at 115-130 ยฐC, a series of l-alkenylsilanes of general formula CH 3 (CH 2 ) m CH = CHSiMe 3 ฯช n (OEt) n , where m = 0, 1, and n = 0-3 (1-silyl-1-a