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Ruthenium Catalyzed Deuterium Labelling of α-Carbon in Primary Alcohol and Primary/Secondary Amine in D2O.

✍ Scribed by Masaaki Takahashi; Koichiro Oshima; Seijiro Matsubara


Publisher
John Wiley and Sons
Year
2005
Weight
20 KB
Volume
36
Category
Article
ISSN
0931-7597

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Nucleophilic second-order rate constants, k n ms , for the reactions of several primary and secondary amines with ionized phenyl salicylate (PS Ϫ ) show a nonlinear decrease with the increase in the content of CH 3 CN from 2 to Յ50% v/v in mixed aqueous solvent. The values of k n ms remain almost un