Ruthenium-catalyzed cytochrome P-450 typ
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Shun-Ichi Murahashi; Yoshiaki Oda; Takeshi Naota; Toshiyuki Kuwabara
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Article
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1993
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Elsevier Science
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French
โ 265 KB
The ruthenium-catalyzed oxidation of alkanes with t-bulyl hydroperoxide under mild conditions gives the corresponding ketones and alcohols highly efficiently. Kinetic study revealed lhat tbe reaction involves hydrogen absIraction of oxcsuthenium species.