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Ruthenium-Catalyzed Cyclopropanation of Alkenes Using Propargylic Carboxylates as Precursors of Vinylcarbenoids.

โœ Scribed by Koji Miki; Kouichi Ohe; Sakae Uemura


Publisher
John Wiley and Sons
Year
2004
Weight
172 KB
Volume
35
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Use of carboxylated polyethylene glycol
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Several carboxylated polyethylene glycols as promoters were applied in the platinum-catalyzed hydrosilylation of alkenes, and polyethylene glycol maleic acid monoester as a promoter for hydrosilylation was investigated. It was found that an improvement of the selectivity was achieved in the presence