Ruthenium catalyzed cross-metathesis versus silylative coupling of vinyl and allyl sulfides with vinylsilanes
✍ Scribed by Bogdan Marciniec; Dariusz Chadyniak; Stanisław Krompiec
- Book ID
- 108211377
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 108 KB
- Volume
- 224
- Category
- Article
- ISSN
- 1381-1169
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## In the cross-metathesis reaction of tri(methyl, ethoxy)vinylsilanes with propene and/or 1-butene catalyzed by RuCl 2 (PPh 3 ) 3 activated in benzene at 115-130 °C, a series of l-alkenylsilanes of general formula CH 3 (CH 2 ) m CH = CHSiMe 3 Ϫ n (OEt) n , where m = 0, 1, and n = 0-3 (1-silyl-1-a