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Ruthenium catalysed ethylene—methyl formate reactions. Synthesis of propanol and ketones

✍ Scribed by G. Jenner; A.Ben Taleb

Publisher: Elsevier Science
Year: 1994
Weight: 751 KB
Volume: 91
Category: Article
ISSN: 0304-5102
DOI: 10.1016/0304-5102(94)00031-x

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## Abstract magnified image The reaction of isothiocyanates with __in situ__ generated carbanions of α,β‐unsaturated ketones yielded α,β‐unsaturated keto thioamides which in the reaction with acids or bases cyclized to give 2,6‐disubstituted thiopyran‐4‐ones and in the reaction with α‐bromoesters