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Ruthenium Carbenes Bonded to a Macrocycle: Carbon Monoxide Induced Carbene Migration Pathways from the Metal to the Ligand

✍ Scribed by Alain Klose; Euro Solari; Carlo Floriani; Silvano Geremia; Lucio Randaccio


Book ID
101299361
Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
131 KB
Volume
37
Category
Article
ISSN
0044-8249

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The reaction of 4-X-5-alkylthio-3H-1,2-dithiole-3-thione (1) with Fischer carbene complexes (2) gives, as a main product, cyclohexa dithiine derivatives due to insertion of the carbene ligand into the C3 C4 bond of the heterocycle. The reaction takes place with 1 where the alkyl substituents in posi