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Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM

✍ Scribed by Lutz Ackermann; Alois Fürstner; Thomas Weskamp; Florian J. Kohl; Wolfgang A. Herrmann

Book ID
104261702
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
206 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Chemically quite robust ruthenium carbene complexes 2-8 bearing one or two imidazolin-2ylidene ligands are highly active catalysts for all types of ring closing metathesis reactions (RCM). Importantly, they even allow the formation of tetrasubstituted alkenes that were previously out of reach of ruthenium-based metathesis catalysts.

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