Ruthenium and platinum catalyzed carbon oxidation: A comparative kinetic study
β Scribed by M. Jeguirim; K. Villani; J.F. Brilhac; J.A. Martens
- Book ID
- 103813208
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 320 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0926-3373
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π SIMILAR VOLUMES
The kinetics of Ru(VI)-catalyzed oxidation of 2-propanol by hexacyanoferrate(III) was investigated in alkaline media using a spectrophotometric technique. The reaction shows first order in [Ru(VI)], a Michaelis-Menten-type dependence on [2-propanol], a fractional order in [Fe(CN) 3Γ 6 ] and a compli
The oxidation kinetics of 2-butanol by alkaline hexacyanoferrate(III) catalyzed by sodium ruthenate has been studied spectrophotometrically. The initial rates method was used for kinetic analysis. The reaction rate shows a fractional-order in [hexacyanoferrate(III)] and [substrate] and a first-order
## Abstract RuCl~3~ further catalyzes the oxidation of iodide ion by K~3~Fe(CN)~6~, already catalyzed by hydrogen ions. The rate of reaction, when catalyzed only by hydrogen ions, was separated graphically from the rate when both Ru(III) and H^+^ ions catalyzed the reaction. Reactions studied separ