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Runaway reaction of lauroyl peroxide with nitric acid by DSC

✍ Scribed by Mei-Li You; Jo-Ming Tseng; Ming-Yang Liu; Chi-Min Shu

Publisher
Springer Netherlands
Year
2010
Tongue
English
Weight
272 KB
Volume
102
Category
Article
ISSN
0022-5215

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πŸ“œ SIMILAR VOLUMES

Preparation of adipic acid by oxidation
Preparation of adipic acid by oxidation of cyclohexanol and cyclohexanone with nitric acid: Part I. Reaction mechanism
✍ W. J. van Asselt; D. W. van Krevelen πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 662 KB

## Abstract The oxidation of cyclohexanol with nitric acid to adipic acid proceeds via two stable intermediates known from the literature^1^ viz. 6‐hydroxyimino‐6‐nitro hexanoic acid and the hemihydrate of 1,2‐cyclohexanedione, two substances forming beside each other in a given ratio. This ratio c