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Ruling out harmonic couplings as a possible origin of an anomalous isotope effect on the ν5modes in H bonds

✍ Scribed by G. Auvert; Y. Maréchal


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
278 KB
Volume
69
Category
Article
ISSN
0009-2614

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✦ Synopsis


of the transttlon probablhtles of all the IR bands of adtplc acid crystals, polarized tn the u, c plane and havmg frrquencles UI the range 10004000 cm-' _sho\r that the anomalous value PH/PD = Z found for the ratto of the tran-sItIon probablhues of vs bands O-H 0 and O-D 0 cannot be due to a harmomc couphng of vs vlbrauons with other Wbrarlons