RuIII(edta) mediated oxidation of azide in the presence of hydrogen peroxide. Azide versus peroxide activation
β Scribed by Chatterjee, Debabrata ;Franke, Alicja ;Oszajca, Maria ;van Eldik, Rudi
- Book ID
- 121326219
- Publisher
- Royal Society of Chemistry
- Year
- 2014
- Tongue
- English
- Weight
- 827 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1477-9226
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## Abstract **BACKGROUND:** The combination of electrochemical oxidation using a Ti/RuO~2~ο£ΏIrO~2~ anode with hydrogen peroxide has been used for the degradation of Crystal Violet. The effect of major parameters such as initial pH, hydrogen peroxide concentration, current density, electrolyte concen
Palladium species catalyze the aerobic oxidation of a variety of organic substrates. The reoxidation of palladium(0) to palladium(II) by dioxygen, a necessary step in these catalytic oxidations, results in the simultaneous formation of free peroxide. However, the continued catalytic generation of pe