Ru(III) catalyzed oxidation of some aliphatic alcohols by N-bromosuccinimide (NBS). A kinetic study
โ Scribed by Reddy, P. Giridhar ;Reddy, A. Venkat ;Ratnamala, A. ;Rao, S. Venkateswara ;Kandlikar, Sushama
- Book ID
- 112683298
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 228 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0133-1736
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The kinetics of the oxidation of cyclopentanol, cyclohexanol, 2-methylcyclohexanol, and cycloheptanol by hexacyanoferrate(II1) ions in mild alkaline medium has been studied in the presence of traces of ruthenium(V1) = lO-?M at constant ionic strength (0.26M). The results suggest that the oxidation o
## Abstract The title reaction shows a mixed kinetic order with respect to hexacyanoferrate(III). The reaction tends to be single zero order at high [Fe(CN)] and single first order at low [Fe(CN)]. For this reason, the decay of the absorbance of hexacyanoferrate(III) at 420 nm changes from linear t