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RuCo2(CO)11 und Ru2Co2(CO)13, zwei neue ”reine„ Carbonylmetall-Cluster

✍ Scribed by Eckehart Roland; Prof. Dr. Heinrich Vahrenkamp


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
247 KB
Volume
93
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


RuCo2(CO)11 and Ru2Co2(CO)13, Two New “P
✍ Dipl.-Chem. Eckehart Roland; Prof. Dr. Heinrich Vahrenkamp 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 English ⚖ 226 KB 👁 1 views

If a molar ratio of 1 : 1 is used, then the stable fluorosilanol (2) is formed in high yieldsL4'. At room temperature it forms colorless, readily sublimable crystals. (2) reacts quantitatively with tert-butyllithium with cleavage of isobutane to give the unexpected stable lithium di-tert-butylfluor

Tri- and Tetranuclear Mixed-Metal Cluste
✍ Vincent Ferrand; Georg Süss-Fink; Antonia Neels; Helen Stoeckli-Evans 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 406 KB 👁 2 views

The tetrahedral cluster anion [Ru 3 Ir(CO) 13 ] -(1) reacts with neutral hydrido clusters [HRu 2 Ir(CO) 9 (RCϵCRЈ)] (10: R = RЈ = Ph; 11: R = RЈ = Et; 12: R = Ph; RЈ = Me; 13: R = RЈ = Me). internal alkynes RCϵCRЈ to afford the alkyne derivatives [Ru 3 Ir(CO) 11 (RCCRЈ)] -(2: R = RЈ = Ph; 3: R = RЈ