𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rubber toughening in polypropylene: A review

✍ Scribed by J. Z. Liang; R. K. Y. Li


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
133 KB
Volume
77
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

✦ Synopsis


The recent advances in the studies of the toughening methods and theories of polypropylene (PP)-elastomer blends are reviewed in the present article. Inclusions are key to toughening PP; they can play the role of agent-induced crazing, cause shear yielding of the matrix around them, and end the propagation of cracks. The major theories interpreting the toughening mechanisms of the blends are: multiple crazing, damage competition theory, shear-yielding theory, microvoids, and cavitation theories. The factors affecting the toughening effect are relatively complicated. Therefore, these theories have been verified only in some cases when they have been applied in relevant conditions. To achieve the objective of better toughening, it is important to improve the uniform distribution of dispersed-phase particle size and suitable filler size, as well as improving the dispersion of the inclusions formed in the matrix; in addition the matrix materials or fillers must be functional with suitable modifier in order to enhance the interfacial adhesion or to improve the interfacial morphological structure between the filler and matrix. However, the exact toughening mechanisms for PP-rubber blends have to be studied further because of complications resulting from the crystallinity of the matrix.


πŸ“œ SIMILAR VOLUMES


Spherulite boundary strengthening concep
✍ A. Lustiger; C. N. Marzinsky; R. R. Mueller πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 416 KB

During spherulitic crystallization of polymers, there is a tendency for low molecular weight and other less crystallizable entities to be rejected from the body of the spherulites. This rejection process causes a segregation of these species to those areas where spherulites impinge. As a result of t

Thermal properties and crystallization b
✍ Dachun Sun; Qiang Yuan; Wei Jiang πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 184 KB πŸ‘ 1 views

## Abstract Thermal properties and crystallization behavior of ultrafine fully‐vulcanized powdered rubber (UFPR) toughened polypropylene (PP) were studied by Differential scanning calorimetry (DSC) and Wide angle X‐ray diffraction (WAXD) measurements. It was found that the fraction of β‐form in the

Thermoplastic toughening of epoxy resins
✍ J. H. Hodgkin; G. P. Simon; R. J. Varley πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 299 KB πŸ‘ 2 views

Thermoplastic toughening of epoxy resins has been actively studied since the early 1980s with considerable progress in property improvement and understanding having been made since then. The main advantage in using thermoplastics to toughen epoxy resins is that their incorporation need not result in