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[Ru2(μ-4-F-C6H4CO2)2(CO)5H2O]: Molecular structure and catalytic activity

✍ Scribed by M. Rotem; I. Goldberg; Y. Shvo


Book ID
108328337
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
161 KB
Volume
97
Category
Article
ISSN
0020-1693

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## Abstract The cobaltocenium salts [Co{C~5~H~4~(B__i__Pr~2~)}~2~]PF~6~ [(1a)PF~6~] and [Co{C~5~H~4~(BMe~2~)}~2~]PF~6~ [(1b)PF~6~] are strong Lewis acids. With pyridine (1a)PF~6~ forms a mono‐adduct 2 and a di‐adduct 3 which show NMR spectra in the low‐temperature regime of pyridine exchange. With