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Ru-Catalyzed Oxidation of Acetylenes to α-Diketones with Iodosylbenzene

✍ Scribed by Paul Müller; José Godoy

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
163 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Disubstituted acetylenes are oxidized with PhIO in presence of Ru‐catalysts to afford α‐diketones in 65–85% yield. Under the same conditions terminal acetylenes are cleaved to carboxylic acids.

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