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Rovibrational Spectroscopy of the v5 = 1 Level of 28SiDF3

✍ Scribed by P. Pracna; L. Margulès; J. Cosléou; J. Demaison; E.B. Mkadmi; H. Bürger

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
95 KB
Volume
199
Category
Article
ISSN
0022-2852

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✦ Synopsis

The 5 fundamental band of trifluorosilane-d (SiDF 3 ) at 627 cm Ϫ1 was studied for the first time by high-resolution FTIR spectroscopy at a resolution of 2.4 ϫ 10 Ϫ3 cm Ϫ1 . The analysis was performed simultaneously with available microwave and newly measured submillimeter-wave data in the approximation of an isolated degenerate fundamental level of a C 3v symmetric top molecule leading to a standard deviation of 0.22 ϫ 10 Ϫ3 cm Ϫ1 for the reproduction of the infrared wavenumbers, 36 kHz for the microwave, and 198 kHz for the submillimeter-wave frequencies, respectively. The unitary equivalence between the two reductions (Q and D) of the effective Hamiltonian applied in the analysis is demonstrated.

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