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Rovibrational energies, partition functions and equilibrium fractionation of the CO2 isotopologues

✍ Scribed by Cerezo, J.; Bastida, A.; Requena, A.; Zúñiga, J.

Book ID
125800539
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
818 KB
Volume
147
Category
Article
ISSN
0022-4073

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📜 SIMILAR VOLUMES

Relation between non-equilibrium effects
Relation between non-equilibrium effects and the activation energy of a unimolecular reaction: low pressure decomposition of CO2
✍ D.C. Tardy 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 326 KB

The observed activation of energy for a unimolecular reaction in the low pressure limit deviates from the high pressure activation energy by two contributing factors; these factors are discussed and applied to the decomposition of CO2. The correction is found to be approximately 30 kcal.