✦ LIBER ✦

Rotation—vibration scalar coupling χ coefficients and spectroscopic band shapes of buckminsterfullerene

✍ Scribed by David E. Weeks; William G. Harter

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 555 KB
Volume: 176
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(91)90156-4

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✦ Synopsis

The Maxwell-Boltzmann distribution IS used to calculated,,,,, for the proposed icosahedrally symmetric structure of Cm called buckminsterfullerene. The results are used with calculated rotation-vibration scalar coupling [coefficients to make predictions for the dipole active rovibrational band shapes. Stereoscopic figures of the corresponding normal modes are shown in the body fired rotating frame. Rotational constants and spectral features of CH,, CF,, and SF6 are included for comparison.