✦ LIBER ✦

Rotationally resolved spectroscopy on the 1-cyanonaphthalene/triethylamine van der Waals complex in a molecular beam

✍ Scribed by Giel Berden; W.Leo Meerts

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 511 KB
Volume: 224
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00551-6

No coin nor oath required. For personal study only.

✦ Synopsis

The rotationally resolved fluorescence excitation spectrum of the @ band in the S,tSo transition, at = 318 nm, of the Icyanonaphthalene/triethylamine van der Waals complex has been recorded using laser-induced fluorescence in a molecular beam apparatus. This spectrum could be fitted to a pure a-type band. From the rotational constants a T-shaped geometry could be deduced.

📜 SIMILAR VOLUMES

Intermolecular exciplex induced by the f

Intermolecular exciplex induced by the formation of 1-cyanonaphthalene/triethylamine van der Waals complex in a molecular beam

✍ Hiroyuki Saigusa; Michiya Itoh 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 375 KB

We report on the firsr obxrvaGon of the csciples fluorssccnce via van dzr Waals complex lbrmation of l-cyanonaphthalcnc and triethyhminc in a supersonic molecular bcarn. The formarion of van der Waals complex is evidenced to play an important role in the esciples formation. The cffecl of escitation