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Rotationally resolved electronic spectra for uranium monoxide

✍ Scribed by Michael C. Heaven; Jean-Philippe Nicolai; Stephen J. Riley; Eric K. Parks

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 510 KB
Volume: 119
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)80065-8

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✦ Synopsis

The electronic specu-wn or UO hze been smdicd in the region rrom 16600 zo Xi550 cm-'. A pulsed Irer jet cqwnsion was used to generale low-lemperature (130 K) gas-phax samples of L"9 and UlhO Spectra were recorded by the use of NW-color resonance-enhanced pholoioni~lio~ rollowed b> mass analysis. Three bands have been ro~ammally analysed. providing an eleclronic growid-state rolalional constant oI' 8"s 0 3333i3 cm-' and an O"= 4 .issxgnment Thtiss rcsull~ are shown 10 be m good agreement with the cm-rem rhrorckal models for the etecrronic swucfure of UO_

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Clcwon cncrgy spcclr.~ of (2 +2)-photon ionuaoon of NO arc rcponcd. The intermcdiatc rcsonsnce is A \*S+;lnd scans xc nude over the rot.~t~on~l width of u = 0 and 1. A new type of spectrometer is used accepting ?rr sr at a rcsolutlon of 15 mrV The VlbratlonJl distrrbution peaks at AU = 0 (Frartck-Co