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Rotationally inelastic molecule–surface scattering: dynamical lie algebraic method

✍ Scribed by Yujun Zheng; Xizhang Yi; Daren Guan


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
269 KB
Volume
76
Category
Article
ISSN
0020-7608

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✦ Synopsis


The rotationally inelastic molecule-surface scattering is analyzed using dynamical Lie algebraic method. We treat, by example, the simple model of the scattering of NO from a rigid, flat Ag(111) surface. The explicit expressions of transition probability and the probability current density are obtained. It is proved that dynamical Lie algebraic method can be useful for describing the scattering problems.


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The Lie algebraic approach of Alhassid and Levine Phys. Rev. A 18, 89 ## Ž .x 1978 is applied to the molecule᎐surface scattering. Specially, the diffractionally and rotationally inelastic scattering of a diatomic molecule from a solid surface is dealt with. Within the framework of the close-coupl