𝔖 Bobbio Scriptorium
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Rotational vs vibrational relaxation in the ν(CO) bands of metal carbonyls

✍ Scribed by M. Vermeulen; G. Michel; J. Nasielski


Book ID
113374396
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
285 KB
Volume
35
Category
Article
ISSN
1386-1425

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📜 SIMILAR VOLUMES


Population relaxation of CO(v = 1 ) vibr
✍ E.J. Heilweil; R.R. Cavanagh; J.C. Stephenson 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 791 KB

Picosecond infrared saturation-recovery experiments were performed to obtain measurements of the vibrational energy lifetimes ( r, ) of CO( v= 1) vibrations (Y GZ 1920-l 985 cm-' ) of carbonyl-containing metal complexes in dilute, room-temperature solutions. For relaxation of the F,, CO-stretching v

Validity of the rotational sudden approx
✍ R.J. Price; D.C. Clary; G.D. Billing 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 437 KB

Calculations of cross sections and rate constants are reported for the vibrationti relaution of CO in collision sith 3He and 4He. Results computed using a semiclassical technique and a vibrational close-coupling. rotational infmitearder sudden method are compared.