Rotational vs vibrational relaxation in the ν(CO) bands of metal carbonyls
✍ Scribed by M. Vermeulen; G. Michel; J. Nasielski
- Book ID
- 113374396
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 285 KB
- Volume
- 35
- Category
- Article
- ISSN
- 1386-1425
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📜 SIMILAR VOLUMES
Picosecond infrared saturation-recovery experiments were performed to obtain measurements of the vibrational energy lifetimes ( r, ) of CO( v= 1) vibrations (Y GZ 1920-l 985 cm-' ) of carbonyl-containing metal complexes in dilute, room-temperature solutions. For relaxation of the F,, CO-stretching v
Calculations of cross sections and rate constants are reported for the vibrationti relaution of CO in collision sith 3He and 4He. Results computed using a semiclassical technique and a vibrational close-coupling. rotational infmitearder sudden method are compared.